{"id":1273,"date":"2024-06-03T14:59:17","date_gmt":"2024-06-03T06:59:17","guid":{"rendered":"https:\/\/www.dmaee.org\/archives\/1273"},"modified":"2024-06-03T14:59:17","modified_gmt":"2024-06-03T06:59:17","slug":"%e4%ba%8c%e8%8b%af%e5%9f%ba%e6%b0%a8%e5%9f%ba%e7%94%b2%e9%85%b0%e6%b0%af","status":"publish","type":"post","link":"https:\/\/www.dmaee.org\/archives\/1273","title":{"rendered":"\u4e8c\u82ef\u57fa\u6c28\u57fa\u7532\u9170\u6c2f"},"content":{"rendered":"<p>    \t\t\t\t\t\t<img decoding=\"async\" src=\"http:\/\/staticv5.basechem.org\/img\/tupu\/old\/76e82db6170b4e9e8928cd5c691d6a84.gif\" alt=\"\u4e8c\u82ef\u57fa\u6c28\u57fa\u7532\u9170\u6c2f\u7ed3\u6784\u5f0f\"><\/p>\n<p>\u7ed3\u6784\u5f0f<\/p>\n<table class=\"summary-table table table-striped table-bordered\">\n<col width=\"90\" \/>\n<tbody>\n<tr>\n<th scope=\"row\">\u7269\u7ade\u7f16\u53f7<\/th>\n<td>01T9<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u5f0f<\/th>\n<td>C13H10ClNO<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u91cf<\/th>\n<td>231.68<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u6807\u7b7e<\/th>\n<td>\n<p>                        \u4e8c\u82ef\u57fa\u6c28\u57fa\u7532\u78b3\u6c2f,<\/p>\n<p>                        \u4e8c\u7532\u80fa\u57fa\u7532\u9170\u6c2f,<\/p>\n<p>                        N,N-\u4e8c\u82ef\u57fa\u6c2f\u7532\u9170\u80fa,<\/p>\n<p>                        \u4e8c\u82ef\u7532\u6c28\u9170\u6c2f,<\/p>\n<p>                        \u4e8c\u82ef\u57fa\u6c28\u57fa\u7532\u9170\u6c2f,<\/p>\n<p>                        Chloroformic acid diphenylamide,<\/p>\n<p>                        DPC-Cl<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<ul class=\"nav nav-tabs\">\n<li class=\"active\"><a href=\"#bh\">\u7f16\u53f7\u7cfb\u7edf<\/a><\/li>\n<li><a href=\"#wx\">\u7269\u6027\u6570\u636e<\/a><\/li>\n<li><a href=\"#dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#st\">\u751f\u6001\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/a><\/li>\n<li><a href=\"#js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/a><\/li>\n<li class=\"dropdown pull-right\">\n                    <a href=\"\" class=\"dropdown-toggle\" data-toggle=\"dropdown\">\u66f4\u591a <span class=\"caret\"><\/span><\/a><\/p>\n<ul class=\"dropdown-menu\" role=\"menu\">\n<li><a href=\"#xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/a><\/li>\n<li><a href=\"#zc\">\u8d2e\u5b58\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#hc\">\u5408\u6210\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#yt\">\u7528\u9014<\/a><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<h2 id=\"bh\">\u7f16\u53f7\u7cfb\u7edf<\/h2>\n<p><b>CAS\u53f7\uff1a<\/b>83-01-2<\/p>\n<p><b>MDL\u53f7\uff1a<\/b>MFCD00000633<\/p>\n<p><b>EINECS\u53f7\uff1a<\/b>201-450-2<\/p>\n<p><b>RTECS\u53f7\uff1a<\/b>EY5065000<\/p>\n<p><b>BRN\u53f7\uff1a<\/b>515312<\/p>\n<p><b>PubChem\u53f7\uff1a<\/b>24866819<\/p>\n<h2 id=\"wx\">\u7269\u6027\u6570\u636e<\/h2>\n<p><p>1. \u6027\u72b6\uff1a\u767d\u8272\u7c89\u672b<\/p>\n<p>2. \u5bc6\u5ea6\uff08g\/mL,25\/4\u2103\uff09\uff1a \u672a\u786e\u5b9a<\/p>\n<p>3. \u76f8\u5bf9\u84b8\u6c7d\u5bc6\u5ea6\uff08g\/mL,\u7a7a\u6c14=1\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>4. \u7194\u70b9\uff08\u00baC\uff09\uff1a85<\/p>\n<p>5. \u6cb8\u70b9\uff08\u00baC,\u5e38\u538b\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>6. \u6cb8\u70b9\uff08\u00baC,5.2kPa\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>7. \u6298\u5c04\u7387\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>8. \u95ea\u70b9\uff08\u00baC\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>9. \u6bd4\u65cb\u5149\u5ea6\uff08\u00ba\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>10. \u81ea\u71c3\u70b9\u6216\u5f15\u71c3\u6e29\u5ea6\uff08\u00baC\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>11. \u84b8\u6c14\u538b\uff08kPa,25\u00baC\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>12. \u9971\u548c\u84b8\u6c14\u538b\uff08kPa,60\u00baC\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>13. \u71c3\u70e7\u70ed\uff08KJ\/mol\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>14. \u4e34\u754c\u6e29\u5ea6\uff08\u00baC\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>15. \u4e34\u754c\u538b\u529b\uff08KPa\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>16. \u6cb9\u6c34\uff08\u8f9b\u9187\/\u6c34\uff09\u5206\u914d\u7cfb\u6570\u7684\u5bf9\u6570\u503c\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>17. \u7206\u70b8\u4e0a\u9650\uff08%,V\/V\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>18. \u7206\u70b8\u4e0b\u9650\uff08%,V\/V\uff09\uff1a\u4e0d\u786e\u5b9a<\/p>\n<p>19. \u6eb6\u89e3\u6027\uff1a\u6eb6\u4e8e\u5927\u591a\u6570\u5e38\u89c1\u6eb6\u5242\u4e2d\u3002<\/p>\n<\/p>\n<h2 id=\"dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/h2>\n<p>\n    \t\t\u6682\u65e0\n    \t<\/p>\n<h2 id=\"st\">\u751f\u6001\u5b66\u6570\u636e<\/h2>\n<p>\n    \t\t\u6682\u65e0\n    \t<\/p>\n<h2 id=\"fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/h2>\n<p>\n    \t\t1\u3001&nbsp;&nbsp; \u6469\u5c14\u6298\u5c04\u7387\uff1a65.21 <\/p>\n<p>2\u3001&nbsp;&nbsp; \u6469\u5c14\u4f53\u79ef\uff08cm<sup>3<\/sup>\/mol\uff09\uff1a182.5<\/p>\n<p>3\u3001&nbsp;&nbsp; \u7b49\u5f20\u6bd4\u5bb9\uff0890.2K\uff09\uff1a487.2<\/p>\n<p>4\u3001&nbsp;&nbsp; \u8868\u9762\u5f20\u529b\uff08dyne\/cm\uff09\uff1a50.8<\/p>\n<p>5\u3001&nbsp;&nbsp; \u6781\u5316\u7387\uff0810<sup>-24<\/sup>cm<sup>3<\/sup>\uff09\uff1a25.85<\/p>\n<p>&nbsp;<\/p>\n<\/p>\n<h2 id=\"js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/h2>\n<p><p>1\u3001&nbsp; \u758f\u6c34\u53c2\u6570\u8ba1\u7b97\u53c2\u8003\u503c\uff08XlogP\uff09\uff1a3.8<\/p>\n<p>2\u3001&nbsp; \u6c22\u952e\u4f9b\u4f53\u6570\u91cf\uff1a0<\/p>\n<p>3\u3001&nbsp; \u6c22\u952e\u53d7\u4f53\u6570\u91cf\uff1a1<\/p>\n<p>4\u3001&nbsp; \u53ef\u65cb\u8f6c\u5316\u5b66\u952e\u6570\u91cf\uff1a2<\/p>\n<p>5\u3001&nbsp; \u62d3\u6251\u5206\u5b50\u6781\u6027\u8868\u9762\u79ef\uff08TPSA\uff09\uff1a20.3<\/p>\n<p>6\u3001&nbsp; \u91cd\u539f\u5b50\u6570\u91cf\uff1a 16<\/p>\n<p>7\u3001&nbsp; \u8868\u9762\u7535\u8377\uff1a0<\/p>\n<p>8\u3001&nbsp; \u590d\u6742\u5ea6\uff1a214<\/p>\n<p>9\u3001&nbsp; \u540c\u4f4d\u7d20\u539f\u5b50\u6570\u91cf\uff1a0<\/p>\n<p>10\u3001&nbsp;&nbsp;&nbsp; \u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>11\u3001&nbsp;&nbsp;&nbsp; \u4e0d\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>12\u3001&nbsp;&nbsp;&nbsp; \u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>13\u3001&nbsp;&nbsp;&nbsp; \u4e0d\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf\uff1a0<\/p>\n<p>14\u3001&nbsp;&nbsp;&nbsp; \u5171\u4ef7\u952e\u5355\u5143\u6570\u91cf\uff1a1<\/p>\n<\/p>\n<h2 id=\"xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/h2>\n<p>\n    \t\t\u5177\u6709\u5438\u6e7f\u6027\uff0c\u5e94\u8fdc\u79bb\u5f3a\u78b1\u548c\u5f3a\u6c27\u5316\u5242\uff1b\u6709\u8150\u8680\u6027\uff1b\u4e0e\u4e8c\u7532\u6c28\u57fa\u3001\u4e8c\u4e59\u6c28\u57fa\u3001\u7532\u57fa\u82ef\u6c28\u57fa\u7532\u9170\u6c2f\u4e0d\u540c\uff0cDPC-Cl\u4e0d\u5177\u6709\u81f4\u764c\u6027\u8d28\u3002\n    \t<\/p>\n<h2 id=\"zc\">\u8d2e\u5b58\u65b9\u6cd5<\/h2>\n<p><p>\u5e94\u5bc6\u5c01\u4e8e\u9634\u51c9\u5e72\u71e5\u5904\u4fdd\u5b58<\/p>\n<\/p>\n<h2 id=\"hc\">\u5408\u6210\u65b9\u6cd5<\/h2>\n<p>\n    \t\t\u6682\u65e0\n    \t<\/p>\n<h2 id=\"yt\">\u7528\u9014<\/h2>\n<p><p>1.\u915a\u7c7b\u8bd5\u5242\u3002\u6709\u673a\u5408\u6210\u3002<\/p>\n<p>2.\u4e8c\u82ef\u6c28\u57fa\u7532\u9170\u6c2f(DPC-Cl) \u662f\u4e00\u79cd\u5e38\u7528\u7684\u9170\u5316\u8bd5\u5242\uff0c\u53ef\u7528\u4e8eFriedel-Crafts\u9170\u57fa\u5316\uff1b\u53ef\u4ee5\u9170\u5316\u80fa\u3001\u6c28\u57fa\u9178\u3001\u786b\u9187\u3001\u82ef\u915a\u3001\u7fa7\u9178\u76d0\u7b49\uff1b\u53ef\u7528\u4f5c\u5be1\u6838\u82f7\u9178\u5408\u6210\u65f6\u7684\u4fdd\u62a4\u57fa\uff0c\u5728\u6d53\u6c28\u6c34-\u7532\u9187\u6216NaOH-\u7532(\u4e59)\u9187\u7b49\u4f5c\u7528\u4e0b\u53ef\u8131\u9664\u4fdd\u62a4\u57fa\u3002<\/p>\n<p><strong>\u7fa7\u57fa\u7684\u5f15\u5165<\/strong>&nbsp; \u5728AlCl<sub>3<\/sub>\u50ac\u5316\u4e0b\uff0cDPC-Cl \u53ef\u5728\u82b3\u73af\u4e0a\u5f15\u5165\u4e00\u4e2a\u7fa7\u57fa\u3002\u70f7\u57fa\u6216\u70f7\u6c27\u57fa\u53d6\u4ee3\u7684\u82b3\u73af\u5bb9\u6613\u53d1\u751f\u53cd\u5e94\u3002\u4ea7\u7269\u4e8c\u82ef\u57fa\u9170\u80fa\u7528\u78b1\u6c34\u89e3\uff0c\u518d\u9178\u5316\u53ef\u5f97\u5230\u7fa7\u9178 (\u5f0f\uff11)<sup>[1]<\/sup>\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_120209\/201202091704262809.gif\" alt=\"\" \/><\/p>\n<p><strong>\u4e0e\u6c28\u57fa\u7684\u53cd\u5e94<\/strong>&nbsp; DPC-Cl\u6613\u4e0e\u4e00\u7ea7 (\u5f0f2)<sup>[2]<\/sup>\u3001\u4e8c\u7ea7\u8102\u80aa\u80fa (\u5f0f3)<sup>[3] <\/sup>\u7b49\u53cd\u5e94<sup>[4~7]<\/sup>\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_120209\/201202091705125027.gif\" alt=\"\" \/><\/p>\n<p><strong>\u4e0e\u5def\u57fa\u7684\u53cd\u5e94<\/strong>&nbsp; \u5728\u78b1\u6027\u6761\u4ef6\u4e0b (\u5982NaHCO<sub>3<\/sub>)\uff0c\u5728\u4e59\u9187\u6eb6\u6db2\u4e2dDPC-Cl\u53ef\u4e0e\u786b\u9187\u53cd\u5e94 (\u5f0f4)<sup>[8]<\/sup>\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_120209\/201202091707148430.gif\" alt=\"\" \/><\/p>\n<p><strong>\u7528\u4f5c\u5be1\u805a\u6838\u82f7\u9178\u5408\u6210\u65f6\u7684\u4fdd\u62a4\u57fa<\/strong>&nbsp; \u5728\u5408\u6210\u5be1\u805a\u6838\u82f7\u9178\u65f6\uff0c\u9e1f\u560c\u5464\u6838\u82f7\u7684\u78b1\u57fa\u5bb9\u6613\u53d1\u751f\u526f\u53cd\u5e94\uff0c\u9700\u8981\u52a0\u4ee5\u4fdd\u62a4\uff0cDPC-Cl\u53ef\u4ee5\u5c06\u9e1f\u560c\u5464\u78b1\u57fa\u7684\u70ef\u9187\u5f02\u6784\u4f53\u9170\u57fa\u5316\u800c\u5bf9\u5176\u8fdb\u884c\u4fdd\u62a4\uff0c\u8fd9\u79cd\u65b9\u6cd5\u5728\u5408\u6210\u5177\u6709\u9e1f\u560c\u5464\u78b1\u57fa\u548c\u4e0e\u9e1f\u560c\u5464\u78b1\u57fa\u7c7b\u4f3c\u7684\u6838\u82f7\u5316\u5408\u7269\u65f6<sup>[9~12]<\/sup>\uff0c\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528 (\u5f0f5)\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_120209\/201202091708066168.gif\" alt=\"\" \/><\/p>\n<p><strong>\u4e0e\u542b\u53cc\u952e\u7684\u9187\u7c7b\u5316\u5408\u7269\u7684\u53cd\u5e94<\/strong>&nbsp; DPC-Cl\u53ef\u4e0e\u5305\u542b\u53cc\u952e\u7684\u9187\u7c7b\u5316\u5408\u7269\u53d1\u751f\u916f\u5316\u53cd\u5e94 (\u5f0f6)<sup>[13]<\/sup>\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_120209\/201202091708447185.gif\" alt=\"\" \/><\/p>\n<p><strong>\u4e0e\u53e0\u6c2e\u5316\u94a0\u7684\u53cd\u5e94<\/strong>&nbsp; DPC-Cl\u53ef\u4e0e\u53e0\u6c2e\u5316\u94a0\u53cd\u5e94\uff0c\u751f\u6210\u76f8\u5e94\u7684\u53e0\u6c2e\u5316\u5408\u7269 (\u5f0f7)<sup>[14]<\/sup>\u3002<\/p>\n<p><img decoding=\"async\" src=\"http:\/\/images.basechem.org\/internal\/day_120209\/201202091709197595.gif\" alt=\"\" \/><\/p>\n<\/p>\n<p>    \t\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.newtopchem.com\/archives\/1087\">https:\/\/www.newtopchem.com\/archives\/1087<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.newtopchem.com\/archives\/44928\">https:\/\/www.newtopchem.com\/archives\/44928<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/pc-cat-nem-catalyst-n-ethylmorpholine\/\">https:\/\/www.bdmaee.net\/pc-cat-nem-catalyst-n-ethylmorpholine\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/cas-3030-47-5\/\">https:\/\/www.bdmaee.net\/cas-3030-47-5\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.newtopchem.com\/archives\/745\">https:\/\/www.newtopchem.com\/archives\/745<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.newtopchem.com\/archives\/44674\">https:\/\/www.newtopchem.com\/archives\/44674<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.newtopchem.com\/archives\/44879\">https:\/\/www.newtopchem.com\/archives\/44879<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.morpholine.org\/category\/morpholine\/page\/5395\/\">https:\/\/www.morpholine.org\/category\/morpholine\/page\/5395\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/nt-cat-dmcha-catalyst-cas10144-28-9-newtopchem\/\">https:\/\/www.bdmaee.net\/nt-cat-dmcha-catalyst-cas10144-28-9-newtopchem\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/metal-delay-catalyst\/\">https:\/\/www.bdmaee.net\/metal-delay-catalyst\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7ed3\u6784\u5f0f \u7269\u7ade\u7f16\u53f7 01T9 \u5206\u5b50\u5f0f C13H10ClNO \u5206\u5b50\u91cf 231.68 \u6807\u7b7e \u4e8c\u82ef\u57fa\u6c28\u57fa\u7532\u78b3\u6c2f, \u4e8c\u7532\u80fa\u57fa\u7532\u9170\u6c2f, N,N-\u4e8c\u82ef\u57fa\u6c2f\u7532\u9170\u80fa, \u4e8c\u82ef\u7532\u6c28\u9170\u6c2f, \u4e8c\u82ef\u57fa\u6c28\u57fa\u7532\u9170\u6c2f, Chloroformic acid diphenylamide, DPC-Cl \u7f16\u53f7\u7cfb\u7edf \u7269\u6027\u6570\u636e \u6bd2\u7406\u5b66\u6570\u636e \u751f\u6001\u5b66\u6570\u636e \u5206\u5b50\u7ed3\u6784\u6570 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[997],"_links":{"self":[{"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/posts\/1273"}],"collection":[{"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/comments?post=1273"}],"version-history":[{"count":0,"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/posts\/1273\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/media?parent=1273"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/categories?post=1273"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.dmaee.org\/wp-json\/wp\/v2\/tags?post=1273"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}